Semiconductor memory device and write method of the same

ABSTRACT

A write and erase method of a semiconductor memory device includes a floating gate type transistor having a semiconductor substrate, a gate insulating film formed on the semiconductor substrate, a floating gate electrode formed on the gate insulating film, and a control gate electrode opposing the floating gate electrode with a hollow portion being sandwiched therebetween. A capacitance between the semiconductor substrate and the control gate electrode is controlled by one of an operation of forming, in the hollow portion, an electrical path which electrically connects the floating gate electrode and the control gate electrode, and an operation of eliminating the electrical path.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is based upon and claims the benefit of priority fromprior Japanese Patent Application No. 2007-011877, filed Jan. 22, 2007,the entire contents of which are incorporated herein by reference.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a floating gate type nonvolatilesemiconductor memory device and a write method of the same.

2. Description of the Related Art

In an n-type memory cell of the conventional NAND flash memory having afloating gate, data write, erase, and read are performed as follows.

In data write, a high positive voltage is applied to a control gateelectrode to inject electric charge into a floating gate electrode froma channel below the floating gate electrode through a tunnel oxide filmby FN tunneling. This increases the threshold voltage of a celltransistor. In data erase, a positive voltage is applied to a substrateto extract electrons from the floating gate electrode to the substrateby FN tunneling. This decreases the threshold voltage of the celltransistor. In data read, the data is discriminated by the amount ofelectric current when a voltage is applied to an arbitrary control gateelectrode.

In the conventional charge storage flash memory as described above, aso-called Yupin effect in which the apparent threshold voltage changesdue to the influence of electric charge in an adjacent floating gateelectrode is unavoidable, and this Yupin effect deteriorates theoperation characteristics of a cell. Also, the Yupin effect occurring inthe conventional charge storage transistor becomes notable as themicropatterning of cells advances. This complicates circuit operations,and makes the micropatterning of cells difficult.

Note that prior art reference information related to the presentinvention is as follows.

[Non-patent Reference 1] K. Terabe, T. Hasegawa, T. Nakayama & M. Aono.Quantized conductance atomic switch. Nature 433, 47-50 (2005)

BRIEF SUMMARY OF THE INVENTION

A write and erase method of a semiconductor memory device according tothe first aspect of the present invention comprising a floating gatetype transistor having a semiconductor substrate, a gate insulating filmformed on the semiconductor substrate, a floating gate electrode formedon the gate insulating film, and a control gate electrode opposing thefloating gate electrode with a hollow portion being sandwichedtherebetween, wherein a capacitance between the semiconductor substrateand the control gate electrode is controlled by one of an operation offorming, in the hollow portion, an electrical path which electricallyconnects the floating gate electrode and the control gate electrode, andan operation of eliminating the electrical path.

A semiconductor memory device according to the second aspect of thepresent invention comprising a floating gate type transistor having asemiconductor substrate, a gate insulating film formed on thesemiconductor substrate, a floating gate electrode formed on the gateinsulating film, and a control gate electrode opposing the floating gateelectrode with a hollow portion being sandwiched therebetween, wherein acapacitance between the semiconductor substrate and the control gateelectrode is controlled by one of an operation of forming, in the hollowportion, an electrical path which electrically connects the floatinggate electrode and the control gate electrode, and an operation ofeliminating the electrical path.

A semiconductor memory device according to the third aspect of thepresent invention comprising a semiconductor substrate, an insulatinglayer formed on the semiconductor substrate, an SOI layer formed on theinsulating layer, a first gate insulating film formed on an uppersurface of the SOI layer, a floating gate electrode formed on the firstgate insulating film, a control gate electrode opposing the floatinggate electrode with a hollow portion being sandwiched therebetween, asecond gate insulating film formed on a lower surface of the SOI layer,a back gate electrode formed below the floating gate electrode so as tosandwich the second gate insulating film, and a diffusion layer formedin the SOI layer between the back gate electrode and the floating gateelectrode.

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING

FIG. 1 is a sectional view showing the basic structure of a memory cellof a semiconductor memory device according to an embodiment of thepresent invention;

FIG. 2 is a sectional view showing a memory cell of a semiconductormemory device according to an embodiment of the present invention;

FIG. 3 is a sectional view showing another memory cell of thesemiconductor memory device according to the embodiment of the presentinvention;

FIG. 4 is a schematic view for explaining the first write method of thesemiconductor memory device according to the embodiment;

FIG. 5 is a schematic view for explaining the second write method of thesemiconductor memory device according to the embodiment;

FIG. 6A is a plan view showing a memory cell array of a NAND flashmemory according to prior art;

FIG. 6B is a sectional view taken along a line VIB-VIB in FIG. 6A;

FIG. 7 is a sectional view showing a memory cell array of a NAND flashmemory according to the first embodiment of the present invention;

FIG. 8 is a sectional view showing a memory cell array of a NAND flashmemory according to the second embodiment of the present invention; and

FIG. 9 is a view for explaining the write operation of the NAND flashmemory according to the second embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

Embodiments of the present invention will be explained below withreference to the accompanying drawing. In the following explanation, thesame reference numerals denote the same parts throughout the drawing.

An embodiment of the present invention to be explained below isapplicable to a nonvolatile semiconductor memory device, e.g., afloating gate type flash EEPROM.

[1] Basic Structure

FIG. 1 is a sectional view showing the basic structure of a memory cellof a semiconductor memory device according to the embodiment of thepresent invention. The basic structure of the memory cell of thesemiconductor memory device according to the embodiment of the presentinvention will be explained below.

As shown in FIG. 1, a gate insulating film 12 is formed on asemiconductor substrate 11, and source/drain diffusion layers 13 areformed in the semiconductor substrate 11. A floating gate electrode FGis formed on the gate insulating film 12. A control gate electrode CG isformed above the floating gate electrode FG so as to oppose it. Aninterlayer portion 10 is formed between the floating gate electrode FGand control gate electrode CG.

A transistor Tr having the basic structure as described above is usedin, e.g., a floating gate type memory cell. While the conventionalfloating gate type flash memory uses a charge storage transistor, thisembodiment uses a non-charge storage transistor.

That is, in the conventional device, the threshold value of the celltransistor is controlled by manipulating the charge amount in thefloating gate electrode by injecting electric charge into anddischarging electric charge from the floating gate electrode. In thisembodiment, however, the threshold value of a memory cell is controllednot by manipulating the charge amount in the floating gate electrode FG,but by manipulating the capacitance between the control gate electrodeCG and the semiconductor substrate 11 of the cell transistor Tr bycontrolling the generation and elimination of an electrical path betweenthe floating gate electrode FG and control gate electrode CG.

To implement the non-charge storage transistor Tr as described above,the interlayer portion 10 sandwiched between the control gate electrodeCG and floating gate electrode FG is given a structure capable ofexchanging electric charge with the electrodes CG and FG on the twosides. More specifically, the following structure is desirable.

(a) The interlayer portion 10 desirably comprises a solid electrolytelayer and hollow portion, and largely changes its resistance value(insulator

conductor) by exchanging electric charge with the control gate electrodeCG and floating gate electrode FG.

(b) The solid electrolyte is desirably Ag₂S, Ag₂Se, Cu₂S, or Cu₂Se.

[2] Embodiment

The structures and operations of the transistor Tr according to anembodiment for implementing the above basic structure will be explainedbelow.

[2-1] Structures

FIGS. 2 and 3 are sectional views of memory cells of a semiconductormemory device according to the embodiment of the present invention. Thestructures of the memory cells of the semiconductor memory deviceaccording to the embodiment of the present invention will be explainedbelow.

In the structure shown in FIG. 2, a gate insulating film 12 is formed ona semiconductor substrate 11, and source/drain diffusion layers 13 areformed in the semiconductor substrate 11. A floating gate electrode FGis formed on the gate insulating film 12, and a control gate electrodeCG is formed above the floating gate electrode FG. The control gateelectrode CG comprises a solid electrolyte layer 31 made of a solidelectrolyte, and a conductive layer 32 made of a conductive material.The solid electrolyte layer 31 is formed in the lower portion (on theside of a hollow portion 20), and the conductive layer 32 is formed inthe upper portion. The solid electrolyte layer 31 and conductive layer32 are in contact with each other. The hollow portion 20 is formedbetween the solid electrolyte layer 31 and floating gate electrode FG.

In the structure shown in FIG. 3, a gate insulating film 12 is formed ona semiconductor substrate 11, and source/drain diffusion layers 13 areformed in the semiconductor substrate 11. A floating gate electrode FGis formed on the gate insulating film 12, and a control gate electrodeCG is formed above the floating gate electrode FG. The floating gateelectrode FG comprises a solid electrolyte layer 31 made of a solidelectrolyte, and a conductive layer 32 made of a conductive material.The solid electrolyte layer 31 is formed in the upper portion (on theside of a hollow portion 20), and the conductive layer 32 is formed inthe lower portion. The solid electrolyte layer 31 and conductive layer32 are in contact with each other. The hollow portion 20 is formedbetween the solid electrolyte layer 31 and control gate electrode CG.

Referring to FIG. 2, the solid electrolyte layer 31 of the control gateelectrode CG is made of Ag₂S, Ag₂Se, Cu₂S, or Cu₂Se, and the conductivelayer 32 of the control gate electrode CG is made of a cation metalelement of the solid electrolyte layer 31. The floating gate electrodeFG is made of a conductive material. When silver sulfide (Ag₂S) is usedas the solid electrolyte layer 31, for example, the conductive layer 32is silver (Ag), and the floating gate electrode FG is one of Al, Cu, Pt,Au, Ag, W, Ni, Co, and poly-Si.

Referring to FIG. 3, the solid electrolyte layer 31 of the floating gateelectrode FG is made of Ag₂S, Ag₂Se, Cu₂S, or Cu₂Se, and the conductivelayer 32 of the floating gate electrode FG is made of a cation metalelement of the solid electrolyte layer 31. The control gate electrode CGis made of a conductive material. When silver sulfide (Ag₂S) is used asthe solid electrolyte layer 31, for example, the conductive layer 32 issilver (Ag), and the control gate electrode CG is one of Al, Cu, Pt, Au,Ag, W, Ni, Co, and poly-Si.

The solid electrolyte layer 31 and conductive layer 32 may have the samefilm thickness or different film thicknesses. The film thicknesses ofthe solid electrolyte layer 31 and conductive layer 32 are desirably,e.g., 2 to 200 nm.

The hollow portion 20 is desirably evacuated or filled with an inertgas. Examples of the inert gas are nitrogen (N₂), argon (Ar), xenon(Xe), and neon (Ne).

The width of the hollow portion 20 (the distance between the floatinggate electrode FG and control gate electrode CG) is preferably 2 nm ormore. This is so because if the width has this value, no directtunneling occurs, and FN tunneling occurs when an electric field ofabout 7 MeV/cm is generated between the floating gate electrode FG andcontrol gate electrode CG.

An example of the material of the gate insulating film 12 is SiO₂.

Note that in actual device construction, the width of the hollow portion20 is preferably 2 to 10 nm when the write characteristics andreliability are taken into consideration. Note also that the width ofthe hollow portion 20 is preferably 4 to 10 nm when SiO₂ is used as thegate insulating film 12.

[2-2] Write Operations

Write operations will be explained below by taking the case where silversulfide (Ag₂S) is used as the solid electrolyte layer 31 and silver (Ag)is used as the conductive layer 32 as an example.

(First Write Operation)

The first write operation is an operation of forming an electrical pathfrom the state in which the hollow portion 20 has no electrical path.That is, this operation increases the capacitance between the controlgate electrode CG and the semiconductor substrate 11 of the celltransistor Tr, and decreases a threshold voltage Vth of the celltransistor Tr.

FIG. 4 is a schematic view for explaining the first write operation ofthe semiconductor memory device according to the embodiment of thepresent invention. The first write operation of the semiconductor memorydevice according to the embodiment of the present invention will beexplained below.

First, the initial state will be explained. In the initial state, thehollow portion 20 between the floating gate electrode FG and controlgate electrode CG has no electrical path. Therefore, twoseries-connected capacitors C1 and C2 exist. That is, the parallel platecapacitor C1 is formed between the floating gate electrode FG andsemiconductor substrate 11, and the parallel plate capacitor C2 isformed between the floating gate electrode FG and control gate electrodeCG.

In the initial state as described above, no electric current Id flowsunless a voltage higher than a predetermine value V1 is applied to thecontrol gate electrode CG, as indicated by an Id-Vg curve. That is, thethreshold voltage V1 of the transistor Tr is held high.

Next, the state when a voltage is applied will be explained. To apply avoltage higher than that of the semiconductor substrate 11 to thecontrol gate electrode CG, the semiconductor substrate 11 is set at 0V,and a positive voltage Vpp is applied to the control gate electrode CG.The positive voltage Vpp is a voltage (e.g., 20V) sufficient to cause FNtunneling of electrons between the floating gate electrode FG andsemiconductor substrate 11, and between the floating gate electrode FGand control gate electrode CG.

When the voltage application described above is performed, electrons eflowing from the semiconductor substrate 11 or floating gate electrodeFG to the control gate electrode CG enter the solid electrolyte layer(Ag₂S) 31. This causes a reduction reaction of silver on that surface ofthe solid electrolyte layer (Ag₂S) 31, which is in contact with thehollow portion 20, and silver atoms deposit. That is, a silver atomfilament 21 is formed on that surface of the solid electrolyte layer(Ag₂S) 31, which is in contact with the hollow portion 20.

When the electrons e are kept injected into the solid electrolyte layer(Ag₂S) 31, the silver atoms keep depositing. In this state, theconductive layer (Ag) 32 supplies silver to make up for the deficiencyof silver in the solid electrolyte layer (Ag₂S) 31. The silver atomfilament 21 grows toward the floating gate electrode FG, and eventuallycomes in contact with the floating gate electrode FG. In this state, thefloating gate electrode FG and control gate electrode CG areelectrically connected. This operation is performed using the samephenomenon as described in non-patent reference 1, and the contact stateis maintained even after the voltage application.

In this electrical path formation, the parallel plate capacitor C1between the floating gate electrode FG and semiconductor substrate 11 isthe capacitor between the control gate electrode CG and semiconductorsubstrate 11. In the electrical path formation, therefore, thecapacitance between the control gate electrode CG and the semiconductorsubstrate 11 of the cell transistor Tr increases from that in theinitial state. Accordingly, as indicated by the Id-Vg curve, theelectric current Id flows through the control gate electrode CG by theapplication of a voltage V2 lower than the voltage V1.

As described above, the first write operation forms the electrical path(silver atom filament 21) in the hollow portion 20. Consequently, theId-Vg curve shifts in the negative direction, and the threshold valueVth of the cell transistor Tr decreases. Note that this change in Id-Vgcurve has the same effect as that of erase in the charge storage flashmemory.

(Second Write Operation)

The second write operation is an operation of eliminating an electricalpath from the state in which the electrical path exists in the hollowportion 20. That is, the second write operation reduces the capacitancebetween the control gate electrode CG and the semiconductor substrate11, and raises the threshold voltage Vth of the cell transistor Tr.

FIG. 5 is a schematic view for explaining the second write operation ofthe semiconductor memory device according to the embodiment of thepresent invention. The second write operation of the semiconductormemory device according to the embodiment of the present invention willbe explained below.

First, the initial state will be explained. In the initial state, theelectrical path (silver atom filament 21) is formed in the hollowportion 20 between the floating gate electrode FG and control gateelectrode CG. Therefore, the parallel plate capacitor C1 is formedbetween the floating gate electrode FG and semiconductor substrate 11.

In the initial state as described above, the threshold voltage V2 of thetransistor Tr is lower than the threshold voltage V1 as indicated by theId-Vg curve.

The state when a voltage is applied will now be explained. To apply avoltage higher than that of the control gate electrode CG to thesemiconductor substrate 11, the control gate electrode CG is set at 0V,and the positive voltage Vpp is applied to the semiconductor substrate11. The positive voltage Vpp is a voltage (e.g., 20V) sufficient toextract the electrons e from the floating gate electrode FG to thesemiconductor substrate 11.

When the voltage application described above is performed, a reductionreaction occurs in the interface between the conductive layer (Ag) 32and solid electrolyte layer (Ag₂S) 31, and an oxidation reaction occursin the interface between the silver atom filament 21 and solidelectrolyte layer (Ag₂S) 31. As a consequence, the silver atom filament21 dissolves in the solid electrolyte layer (Ag₂S) 31.

When the electrons e are kept injected into the semiconductor substrate11, the silver atom filament 21 disappears toward the control gateelectrode CG. Accordingly, the electrical path between the floating gateelectrode FG and control gate electrode CG disappears, so the floatinggate electrode FG and control gate electrode CG are electricallyinsulated.

When the electrical path disappears, two series-connected capacitors C1and C2 are formed. That is, the parallel plate capacitor C1 is formedbetween the floating gate electrode FG and semiconductor substrate 11,and the parallel plate capacitor C2 is formed between the floating gateelectrode FG and control gate electrode CG. When the electrical pathdisappears, therefore, the capacitance between the control gateelectrode CG and the semiconductor substrate 11 of the cell transistorTr reduces from that in the initial state. Accordingly, as indicated bythe Id-Vg curve, the threshold voltage Vth of the cell transistor Trrises.

As described above, the second write operation eliminates the electricalpath (silver atom filament 21) from the hollow portion 20. Consequently,the Id-Vg curve shifts in the positive direction, and the thresholdvalue Vth of the cell transistor Tr increases. Note that this change inId-Vg curve has the same effect as that of write in the charge storageflash memory.

[2-3] Read Operation

This embodiment increases and decreases the capacitance between thecontrol gate electrode CG and the semiconductor substrate 11 of the celltransistor Tr by controlling the generation and elimination of theelectrical path between the floating gate electrode FG and control gateelectrode CG. As a result, the threshold voltage Vth of the celltransistor Tr also changes.

In the read operation, therefore, this phenomenon is used todiscriminate data by the current amount Id when a voltage is applied tothe control gate electrode CG.

[2-4] Application to Nonvolatile Memory Devices

The cases where the above-mentioned memory cell transistor is applied toNAND nonvolatile memory devices will be explained below.

First Embodiment

FIGS. 6A and 6B are views showing three adjacent cells in a memory cellarray of a NAND flash memory according to prior art. FIG. 7 is asectional view showing three adjacent cells in a memory cell array of aNAND flash memory according to the first embodiment to which thenon-charge storage memory cell of the present invention is applied.

As shown in FIG. 6A, an element isolating region 25 extended in thefirst direction is arranged in the plural in the second direction with apredetermine space. An active region AA extended in the first directionso that it may be isolated by this element isolating region 25 isformed. Word lines WL extended in the second direction are arranged witha predetermine space. Select gate lines SGD and SGS are arranged to putthese word lines. A memory cell MT is formed by each of intersection theactive regions AA and word lines WL. A select gate transistor ST isformed by each of intersection the active regions AA and the select gatelines SGD and SGS.

As shown in FIG. 6B, each memory cell of the prior art is a chargestorage transistor Tr having a floating gate electrode FG. An insulatinglayer 33 about 10 nm thick exists between a control gate electrode CGand the floating gate electrode FG. Also, an interlayer dielectric layer34 insulates the individual memory cells. The interlayer dielectriclayer 34 is made of, e.g., SiO₂.

The non-charge storage memory cell (FIG. 2 or 3) of the presentinvention proposed in this specification can be applied to the NANDnonvolatile memory according to the prior art as described above by onlyreplacing each memory cell of the conventional NAND flash memory shownin FIGS. 6A and 6B with the memory cell shown in FIG. 2 or 3.

That is, as shown in FIG. 7, a control gate electrode CG comprises asolid electrolyte layer 31 and conductive layer 32, and a hollow portion20 is formed between the control gate electrode CG and a floating gateelectrode FG.

Note that each memory cell shown in FIG. 7 has the structure shown inFIG. 2, but it may also have the structure shown in FIG. 3.

Second Embodiment

In the NAND nonvolatile memory device shown in FIG. 7 to which thenon-charge storage memory cell is applied, the same NAND cell arraysometimes includes both a cell in which the control gate electrode CGand floating gate electrode FG are electrically connected by a metalfilament, and a cell in which the control gate electrode CG and floatinggate electrode FG are not electrically connected. The former will becalled a “written” cell, and the latter will be called “an erased” cell.

In data write and read, a voltage Vpass or Vread is applied to thecontrol gate electrode CG of an unselected cell in the conventionalcharge storage memory cell array. In the non-charge storage memory cellarray of this embodiment, however, the voltages Vpass and Vread areapplied between a substrate 11 and the floating gate electrode FG of anunselected “written” cell.

Generally, voltage Vpass=8 to 12V and voltage Vread=4 to 6V in theconventional NAND device. In this case, data write is particularly aproblem in this embodiment. More specifically, if FN tunneling occursbetween the substrate 11 and floating gate electrode FG due to thevoltage Vpass in an unselected “written” cell, the channel potential ofa selected NAND cell array to be set at 0V rises, and the electric fieldbetween the substrate 11 and floating gate electrode FG reduces in aselected cell. This may make data write impossible.

In the conventional NAND device, insulating films 12 and 33 are made ofSiO₂, and the film thickness of the insulating films 12 and 33 isappropriately about 10 nm. However, FN tunneling occurs if a voltageVpass of 8 to 12V is applied between the substrate 11 and floating gateelectrode FG. No FN tunneling occurs if it is possible to reduce thevoltage Vpass to, e.g., about 5V. Unfortunately, this reduces the riseof the channel potential in an unselected cell array. If a cellincluding a selected word line in the unselected cell array is an“erased” cell, FN tunneling occurs between the control gate electrode CGand floating gate electrode FG, and between the substrate 11 andfloating gate electrode FG. This may cause unwanted data write.

Accordingly, in the NAND device using the non-charge storage memory cellof this embodiment proposed in this specification, a structure capableof controlling the channel of an unselected cell by an electrode otherthan the control gate electrode CG of the unselected cell is moredesirable from the operational viewpoint than the conventional methodthat turns on the channel of an unselected cell by applying the voltagesVpass and Vread to the control gate electrode CG of the unselected cell.

As a device structure capable of the operation like this, a structurehaving a back gate and an operation method of the structure arepossible. FIG. 8 shows this device structure.

As shown in FIG. 8, an SOI (Silicon On Insulator) layer 35 is formedabove a semiconductor substrate 11. The SOI layer 35 has a filmthickness of, e.g., about 5 to 100 nm, and is made of, e.g.,single-crystal Si or poly-Si. The gate stack structure shown in FIG. 2or 3 is formed on the SOI layer 35 (the structure shown in FIG. 2 isused in FIG. 8).

Transistors Tr-1, Tr-2, and Tr-3 of memory cells MC1, MC2, and MC3respectively have back gates BG-1, BG-2, and BG-3 immediately below thegate stack structures so as to sandwich insulating films 36 betweenthem. The insulating films 36 have a film thickness of, e.g., about 4 to100 nm, and are made of, e.g., SiO₂. Examples of the material of theback gates BG-1, BG-2, and BG-3 are Al, Cu, Pt, Au, Ag, W, Ni, Co, andpoly-Si. The film thickness of the back gates BG-1, BG-2, and BG-3 is,e.g., about 10 to 1,000 nm.

Diffusion layers 13 are formed from the upper surface to the lowersurface of the SOI layer 35. The substrate 11 and back gates BG-1, BG-2,and BG-3 have a spacing of, e.g., 30 to 100 nm, and are insulated by aninterlayer dielectric layer 34.

A write operation will be explained below with reference to FIG. 9. Thememory cells MC1 and MC2 are “written” cells, and the memory cell MC3 isan “erased” cell. An operation of writing data in the memory cell MC2will be explained below.

First, a voltage Vpass of, e.g., 4 to 6V is applied to the back gatesBG-1 and BG-3 of the unselected cells MC1 and MC3. Consequently,channels 37 are formed in the lower portions of the SOI layers 35 of thememory cells MC1 and MC3.

Then, a voltage Vpgm of, e.g., 20V is applied to the conductive layer 32of the control gate electrode CG of the selected cell MC2. In thisstate, 0V is transferred from a bit line to the diffusion layer 13 andchannel 37 of the selected cell MC2 via the channels 37, which areformed by the application of the back gate voltage, of the unselectedcells MC1 and MC2, thereby making data write possible. That is, data canbe written in the selected memory cell MC2 without applying the voltageVpass to the control gate electrode CG of the unselected “written” cellMC1.

In this embodiment as described above, the above-mentioned writeoperation is performed using memory cells having back gates. Even whenan unselected cell is a “written” cell, therefore, the voltage Vpassneed not be applied to the control gate electrode CG of this unselectedcell, so no electrons are injected into the floating gate electrode FGof the unselected cell. This eliminates the possibility of a write errorin a selected cell.

Effects of Embodiments

In the embodiment of the present invention described above, anelectrical path is generated or eliminated between the floating gateelectrode FG and control gate electrode CG by adjusting the applicationvoltage between the control gate electrode CG and semiconductorsubstrate 11. This increases or decreases the capacitance between thecontrol gate electrode CG and semiconductor substrate 11, therebycontrolling the threshold voltage Vth. Thus, the embodiment of thepresent invention can implement the non-charge storage transistor.Therefore, the Yupin effect occurring in the conventional charge storagetransistor does not essentially occur in this embodiment. This makes itpossible to neglect the threshold fluctuation caused by the influence ofelectric charge between adjacent cells.

Also, the Yupin effect occurring in the conventional charge storagetransistor becomes conspicuous as the micropatterning of cellsprogresses. This complicates circuit operations and imposes limitationson the micropatterning. However, this embodiment can avoid theseconventional problems because no Yupin effect occurs.

Furthermore, in the conventional charge storage transistor, it isnecessary to set a sufficient coupling ratio in order to well injectelectrons into the floating gate electrode and well discharge electronsfrom the floating gate electrode. Therefore, each memory cell must havea three-dimensional structure, and this makes processing complicated anddifficult. Consequently, not only the Yupin effect limits themicropatterning of memory cells, but also the process dispersion and theprocess cost unavoidably increases. By contrast, the operation of thisembodiment can be performed by a parallel plate capacitor structure. Aplanar cell structure can simplify the processing, and reduce theprocess dispersion and the process cost.

Note that this embodiment is applicable to both NAND and NOR flashmemories.

Additional advantages and modifications will readily occur to thoseskilled in the art. Therefore, the invention in its broader aspects isnot limited to the specific details and representative embodiments shownand described herein. Accordingly, various modifications may be madewithout departing from the spirit or scope of the general inventiveconcept as defined by the appended claims and their equivalents.

1. A write and erase method of a semiconductor memory device comprisinga floating gate type transistor having: a semiconductor substrate; agate insulating film formed on the semiconductor substrate; a floatinggate electrode formed on the gate insulating film; and a control gateelectrode opposing the floating gate electrode with a hollow portionbeing sandwiched therebetween, wherein one of the floating gateelectrode and the control gate electrode includes a solid electrolytelayer touching the hollow portion, and a conductive layer in contactwith the solid electrolyte layer.
 2. The method according to claim 1,wherein a material of the solid electrolyte layer is one of Ag₂S, Ag₂Se,Cu₂S, and Cu₂Se, and the conductive layer is made of a cation metalelement of the material of the solid electrolyte layer.
 3. The methodaccording to claim 1, wherein the hollow portion is one of a vacuumportion and a portion filled with an inert gas.
 4. The method accordingto claim 1, wherein the semiconductor memory device comprises an EEPROM.5. The method according to claim 1, wherein a capacitance between thesemiconductor substrate and the control gate electrode is controlled byone of an operation of forming, in the hollow portion, an electricalpath which electrically connects the floating gate electrode and thecontrol gate electrode, and an operation of eliminating the electricalpath.
 6. The method according to claim 5, wherein one of the formationand the elimination of the electrical path is performed by applying avoltage between the control gate electrode and the semiconductorsubstrate.
 7. The method according to claim 5, wherein the capacitanceis increased by forming the electrical path in the hollow portion byapplying a voltage higher than that of the semiconductor substrate tothe control gate electrode, and the capacitance is decreased byeliminating the electrical path from the hollow portion by applying avoltage higher than that of the control gate electrode to thesemiconductor substrate.
 8. A semiconductor memory device comprising afloating gate type transistor having: a semiconductor substrate; a gateinsulating film formed on the semiconductor substrate; a floating gateelectrode formed on the gate insulating film; and a control gateelectrode opposing the floating gate electrode with a hollow portionbeing sandwiched therebetween, wherein one of the floating gateelectrode and the control gate electrode includes a solid electrolytelayer touching the hollow portion, and a conductive layer in contactwith the solid electrolyte layer.
 9. The device according to claim 8,wherein a material of the solid electrolyte layer is one of Ag₂S, Ag₂Se,Cu₂S, and Cu₂Se, and the conductive layer is made of a cation metalelement of the material of the solid electrolyte layer.
 10. The deviceaccording to claim 8, wherein the hollow portion is one of a vacuumportion and a portion filled with an inert gas.
 11. The device accordingto claim 8, wherein the semiconductor memory device comprises an EEPROM.12. The device according to claim 8, wherein a capacitance between thesemiconductor substrate and the control gate electrode is controlled byone of an operation of forming, in the hollow portion, an electricalpath which electrically connects the floating gate electrode and thecontrol gate electrode, and an operation of eliminating the electricalpath.